2024年4月27日 星期六
香豆素的1H-NMR检测及其在阿魏亚族化学分类中的应用
Chemotaxonomy of Ferulineae based on the coumarins identified by 1 H-NMR
1999年 第8卷 第1期 页码[46-51]    下载全文[0.7MB]  
摘要

利用1H-NM R 法检测中国阿魏亚族(Ferulineae Drude)8 27 3 变种根部乙醚提取物的香豆素成分类型, 其中主要为线型二氢呋喃型香豆素(Ⅰ)和角型二氢吡喃型香豆素(Ⅳ), 线型二氢吡喃型香豆素(Ⅲ)和角型二氢呋喃型香豆素(Ⅱ)较少据此, 8 属分成 4 :(1)阿魏属(Ferula L.)、球 根 阿魏 属(Schumannia Kuntze)、簇花 芹 属(Soranthus Ledeb.)和 伊犁 芹 属(Talassia Korov.)未测出(不含)香豆素;(2)弓翅芹属(Arcuatopterus Sheh et Shan)和川明参属(Chuanminshen Sheh et Shan);(3)胀果芹属(Phlojodicarpus Turcz.ex Bess.);(4)前胡属(Peucedanum L.)类和上述结果支持将球根阿魏簇花芹和伊犁芹 3 个属并入阿魏属, 3 个寡种属与前胡属关系最密切所分析的前胡属 17 2 变种可分成 5 , 其中不含香豆素的剌尖前胡和含类香豆素的紫花前胡及其变种最特殊, 支持将它们分出前胡属的处理
 

Abstract

The coumarin types of the etherial extracts from 30 root sam ples of 27 species 3 varieties of 8 genera in Ferulineae Drude w ere investigated by 1 H-NM R .There are four coumarin types , in w hich the linear-ty pe dihydrofuranocoum arins (Ⅰ)and the angulartype dihy dropyranocoumarins (Ⅳ) are the main components, the linear-type dihydropy ranocoumarins (Ⅲ)and the angular-type dihy drofuranocoumarins (Ⅱ)are fewer.Eight genera can be divided into 4 groups :(1)Ferula L ., Schumannia Kuntze, Soranthus Ledeb .and Talassia Korov .:without coumarins or unidentified out ;(2)Arcuatopterus Sheh et Shan and Chuanm inshen Sheh et Shan : with coumarinⅠ ;(3)Phlojodicarpus Turcz .ex Bess .:with coumarin Ⅳ;(4)Peucedanum L .:
with coumarins and Ⅳ.Therefore , Schumannia .Soranthus and Talassia
should be incorporated with Ferula , and Peucedanum is closely w ith another three small genera.Because of the peculiar character that coumarin is absent in P .elegans Komarov and coumarin is present in P . decursivum (Miq .)Maxim ., it is suggested that they should be separated from Peucedanum .
 

关键词阿魏亚族; 伞形科; 核磁共振氢谱法; 香豆素; 化学分类
Key wordsFerulineae Drude; Umbelliferae; 1H-NM R; coumarin; chemotaxonomy
作者刘启新1 吴美玉2 饶高雄3 叶锦生1 惠 红1
所在单位1 江 苏 省中国科学院植物研究所, 南京 210014
2江苏省化工研究所, 南京 210024
3云南中医学院, 昆明 650011
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